If there's a villain-turned-hero that people love to the same degree they love Loki (Tom Hiddleston), it's Bucky Barnes (Sebastian Stan). He first appeared in Captain America: The First Avenger as Steve Rogers' (Chris Evans) best friend who never wavered from his side. This already made him incredibly lovable, but he became even more layered and compelling after coming back from the "dead" as the evil and terrifying Winter Soldier in Captain America: The Winter Soldier.
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